Bromido(2,2′:6′,2′′-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate

Autor: Michael I. Kahn, James A. Golen, Arnold L. Rheingold, Linda H. Doerrer
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 65, Iss 9, Pp m1135-m1135 (2009)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536809033248
Popis: The crystal structure of the title compound, [PtBr(C15H11N3)][AuBr2]·(CH3)2SO, exhibits infinite chains of {PtAuPt}∞ metallophilic interactions along the b axis. Two cations and one anion stack in a trimer with a unique Pt...Au distance of 3.3361 (5) Å and Pt...Pt contacts of 3.4335 (6) Å. The remaining [AuBr2]− anion forms no close contacts.
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