Relative reactivity of the dinuclear ruthenium complex [CpRu(CO)2]2 with diphenylselenyl sulphide and diphenyl disulphide

Autor: Wei Xiang Koh, Andrea Paris Gomez, Jiawen Lee, Jasmaadiyah Binte Habib Mohameed, Weng Kee Leong
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Results in Chemistry, Vol 3, Iss , Pp 100159- (2021)
Druh dokumentu: article
ISSN: 2211-7156
DOI: 10.1016/j.rechem.2021.100159
Popis: The reaction of the diruthenium complex [CpRu(CO)2]2 with the diphenyl dichalcogenides was found to proceed through photoinitiation to the [CpRu(CO)2]· radical. Reaction with selenyl sulphide was slower than with disulphide, which has implications for the selective targeting of the enzyme thioredoxin reductase.
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