per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane

Autor: Nicholas Pearce, E. Stephen Davies, Neil R. Champness
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Molecules, Vol 25, Iss 7, p 1627 (2020)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/molecules25071627
Popis: 1,4-dimethoxypillar[5]arene undergoes reversible multielectron oxidations forming stable radical cations, a property retained when incorporated in [2]rotaxanes, suggesting that pillar[5]arenes can be employed as viable, yet unreported, electron donors.
Databáze: Directory of Open Access Journals