Luminescence and Structure of ZnO Grown by Physical Vapor Deposition

Autor: R. García-Gutiérrez, M. Barboza-Flores, D. Berman-Mendoza, R. Rangel-Segura, O. E. Contreras-López
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: Advances in Materials Science and Engineering, Vol 2012 (2012)
Druh dokumentu: article
ISSN: 1687-8434
1687-8442
DOI: 10.1155/2012/872597
Popis: Nanostructured ZnO was deposited on different substrates (Si, SiO2, and Au/SiO2) by an enhanced physical vapor deposition technique that presents excellent luminescent properties. This technique consists in a horizontal quartz tube reactor that uses ultra-high purity Zn and UHP oxygen as precursors. The morphology and structure of ZnO grown in this work were studied by electron microscopy and X-ray diffraction. The XRD patterns revealed the highly crystalline phase of wurtzite polycrystalline structure, with a preferred (1011) growth direction. Room temperature cathodoluminescence studies revealed two features in the luminescence properties of the ZnO obtained by this technique, first a high-intensity narrow peak centered at 390 nm (~3.2 eV) corresponding to a near band-to-band emission, and secondly, a broad peak centered around 517 nm (2.4 eV), the typical green-yellow luminescence, related to an unintentionally doped ZnO.
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