| Autor: |
Laurence Burroughs, John Ritchie, Mkhethwa Ngwenya, Dilfaraz Khan, William Lewis, Simon Woodward |
| Jazyk: |
angličtina |
| Rok vydání: |
2015 |
| Předmět: |
|
| Zdroj: |
Beilstein Journal of Organic Chemistry, Vol 11, Iss 1, Pp 273-279 (2015) |
| Druh dokumentu: |
article |
| ISSN: |
1860-5397 |
| DOI: |
10.3762/bjoc.11.31 |
| Popis: |
1,4-Diols resulting from the double addition of ArCCLi (Ar = Ph, substituted phenyl, 2-thienyl) to ortho-C6H4(CHO)2 undergo cascades to tetracenes on simple admixture of LiHDMS, CS2 and MeI. Acene formation proceeds by [3,3]-sigmatropic rearrangement of xanthate anions followed by 6π electrocyclisations. The reactions are terminated by E2 or anionic Chugaev-type eliminations. Structural packing motifs and electronic properties are reported for the tetracenes. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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