Superficial Modification of the Mg–Zn Biomaterials via Ion Nitriding for Biomedical Applications

Autor: Sergio Gonzaga, Arturo Molina, Rene Guardian, Horacio Martínez, Edna Vázquez-Vélez, Eduardo Lira-Díaz
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Metals, Vol 14, Iss 2, p 203 (2024)
Druh dokumentu: article
ISSN: 14020203
2075-4701
DOI: 10.3390/met14020203
Popis: In the present work, the powder metallurgy (PM) technique was used to synthesize biocompatible alloys Mg95–Zn5, Mg90–Zn10, and Mg85–Zn15 (wt %) under an argon atmosphere that employed stainless-steel vessels and spheres with a milling treatment of 360 rpm during 15 h. The obtained powder was consolidated through a sintering process for subsequent ion nitriding treatment to increase its corrosion resistance and hardness. The synthesized alloys analyzed by Scanning electron microscopy (SEM) images showed a reduction in particle size with increasing grinding time. The X-ray diffraction (XRD) results showed the formation of a MgZn intermetallic phase and, furthermore, that no impurities were found during the grinding process. The surface-modified Mg–Zn alloys showed some improvement in terms of corrosion (Ecorr 26% and Icorr 13%) and microhardness (HV 40%) compared to Mg. Cytotoxicity evaluation was conducted via an MTT ((3-(4,5-DIMETHYLTHIAZOL-2-YL)-2,5-DIPHENYLTETRAZOLIUM BROMIDE)) assay, which revealed that the Mg–Zn alloys and nitrided samples did not exhibit cytotoxicity towards fibroblast cells after 96 h.
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