Common mechanism for helical nanotube formation by anodic polymerization and by cathodic deposition using helical pores on silicon electrodes

Autor: Yuki Maeda, Takumi Yasuda, Kenta Matsuzaki, Yutaka Okazaki, Emilie Pouget, Reiko Oda, Atsushi Kitada, Kuniaki Murase, Guillaume Raffy, Dario M. Bassani, Kazuhiro Fukami
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Electrochemistry Communications, Vol 114, Iss , Pp - (2020)
Druh dokumentu: article
ISSN: 1388-2481
DOI: 10.1016/j.elecom.2020.106714
Popis: We report that platinum-assisted chemical etching formed self-organized helical pores in silicon substrates can be utilized as platforms for the electrochemical production of nanohelices of conducting polymers (polypyrrole) and metals (gold). Surprisingly, the nanohelices thus created are tubes although the polymerization and deposition were carried out by anodic and cathodic reactions, respectively. Based on our results, we propose a common mechanism for the formation of tubular nanohelices by both anodic polymerization and cathodic deposition through the accumulation of reactants in microporous silicon which covers the wall surface of the helical pores. Keywords: Helical pore, Nanohelices, Conducting polymers, Metals, Tubes
Databáze: Directory of Open Access Journals