(Benzylthiolato-κS)phenylmercury(II)
| Autor: | Paras Nath, Manoj K. Bharty, Sushil K. Gupta, Ray J. Butcher, Jerry P. Jasinski |
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| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: | |
| Zdroj: | IUCrData, Vol 2, Iss 4, p x170503 (2017) |
| Druh dokumentu: | article |
| ISSN: | 2414-3146 24143146 |
| DOI: | 10.1107/S241431461700503X |
| Popis: | The title complex, [Hg(C6H5)(C7H7S)], was synthesized from benzyl 4-methylpiperidine-1-carbodithioate. In the complex, the HgII cation binds to a C atom of a phenyl ring and the S atom of a benzylthiolate ligand in a linear coordination geometry. The molecule is bent at the methylene C atom and the S atom, resulting in a syn conformation with respect to the benzyl and phenyl rings. The dihedral angle between the phenyl and benzyl rings is 64.6 (2)°. The crystal structure is stabilized by intermolecular Hg...S [3.290 (3) Å] contacts and C—H...π interactions, generating a three-dimensional network. |
| Databáze: | Directory of Open Access Journals |
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