Formation and degradation of strongly reducing cyanoarene-based radical anions towards efficient radical anion-mediated photoredox catalysis

Autor: Yonghwan Kwon, Jungwook Lee, Yeonjin Noh, Doyon Kim, Yungyeong Lee, Changhoon Yu, Juan Carlos Roldao, Siyang Feng, Johannes Gierschner, Reinhold Wannemacher, Min Sang Kwon
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Nature Communications, Vol 14, Iss 1, Pp 1-15 (2023)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-022-35774-5
Popis: Cyanoarene-based photocatalysts are widely used due to their catalytic performance, but the formation of the active species and its potential degradation pathways are poorly understood. Here, the authors investigate these pathways under commonly-used photoredox-mediated reaction conditions.
Databáze: Directory of Open Access Journals