| Autor: |
D. Dhana Lakshmi, B. Srinivasa Rao, Yogita, N. Lingaiah |
| Jazyk: |
angličtina |
| Rok vydání: |
2021 |
| Předmět: |
|
| Zdroj: |
Materials Science for Energy Technologies, Vol 4, Iss , Pp 357-366 (2021) |
| Druh dokumentu: |
article |
| ISSN: |
2589-2991 |
| DOI: |
10.1016/j.mset.2021.08.012 |
| Popis: |
Selective catalytic hydrodeoxygenation (HDO) of 5-hydroxymethylfurfural (HMF) to prepare 2, 5-dimethylfuran (DMF) was studied as this product is a good biofuel. A sequence of copper dispersed on SBA-15 catalysts are designed and tested their activity for HMF hydrodeoxygenation reaction. The physico-chemical characteristics of the catalysts are gained from powder XRD, TEM, N2-adsorption desorption, NH3-TPD, H2-TPR and N2O-chemisorptions studies. Characterization results indicate the fine dispersion of Cu metal on SBA-15 with high surface area and appropriate acidic sites. The catalyst with 15%Cu on SBA-15 showed high activity towards DMF with 90% yield. The optimized reaction conditions were 180 °C of reaction temperature, 20 bar H2 pressure, and a reaction time of 8 h to achieve maximum yield. The catalyst is recyclable and exhibits consistent activity. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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