(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetraazacyclotetradecane)copper(II) bis[O,O′-(o-phenylene)dithiophosphate]
| Autor: | Chuan Lai, Yang-Guang Xiang, Jian-Shen Feng, Bin Xie, Li-Ke Zou |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 12, Pp m1593-m1593 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810046684 |
| Popis: | In the title compound, [Cu(C16H36N4)](C6H4O2PS2)2, the CuII cation lies on an inversion center and is chelated by the macrocyclic tetraamine ligand in a slightly distorted CuN4 square-planar geometry. The axial positions are occupied by two O,O′-(o-phenylene)dithiophosphate anions with long Cu...S distances of 3.0940 (7) Å. Intermolecular N—H...S and C—H...O hydrogen bonding is present between the anions and the cation and helps to stabilize the crystal structure. |
| Databáze: | Directory of Open Access Journals |
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