Synthetic study on the angular triquinanes

Autor:	Stjepanović Mihailo N., Janković Aleksandar V., Vulović Bojan Z., Matović Radomir V., Saičić Radomir N.
Jazyk:	angličtina
Rok vydání:	2023
Předmět:	cyclopentane natural products organic synthesis wacker oxidation aldol condensation Chemistry QD1-999
Zdroj:	Journal of the Serbian Chemical Society, Vol 88, Iss 10, Pp 975-983 (2023)
Druh dokumentu:	article
ISSN:	0352-5139 1820-7421
DOI:	10.2298/JSC230627046S
Popis:	The synthesis of an angular triquinane, which could serve as a suitable platform for the synthesis of several natural products (panaginsene, silphinene, senoxydene) is described. The synthesis is based on two consecutive cyclopentene annulations, where alkenes were used as latent carbonyl functionalities (via Wacker reaction), and cyclopentenone annulation was effected by aldol condensation.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/20169b0e52974e689147b7d5c6f8ef5a Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF