Use of heterogeneous catalysts in methylic biodiesel production induced by microwave irradiation

Autor: Evandro L. Dall'Oglio, Paulo T. de Sousa Jr, Pedro Tiago de Jesus Oliveira, Leonardo Gomes de Vasconcelos, Carlos Adriano Parizotto, Carlos Alberto Kuhnen
Jazyk: English<br />Spanish; Castilian<br />Portuguese
Rok vydání: 2014
Předmět:
Zdroj: Química Nova, Vol 37, Iss 3, Pp 411-417 (2014)
Druh dokumentu: article
ISSN: 1678-7064
0100-4042
DOI: 10.5935/0100-4042.20140081
Popis: The effect of different heterogeneous catalysts on the microwave-assisted transesterification of sunflower oil for the production of methylic biodiesel in a monomode microwave reactor is described. The experiments were carried out at 70 ºC with a 16:1 methanolsunflower oil molar ratio and different heterogeneous basic and acidic catalysts. The results showed that the microwave-heated reactions occur up to four times faster than those carried out with conventional heating. The reactions were performed with 24 catalysts; pure calcium oxide (CaO) and potassium carbonate, either pure or supported by alumina (K2CO3/Al2O3), were the most efficient catalysts.
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