Bis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)]
| Autor: | Hui-Chang Chang, Jacqueline M. Cole, Tze-Chia Lin, Sven O. Sylvester, Paul G. Waddell |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 6, Pp m690-m690 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811015674 |
| Popis: | The asymmetric unit of the title compound, [Cu2(C12H9N2O)2(C7H5O2)2], contains two independent (2-formylphenolato){2-[(pyridin-2-yl)iminomethyl]phenolato}copper(II) molecules that form pseudocentrosymmetric dimers via interactions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-based pyramidal in the dimer. The crystal studied was an inversion twin, with unequal populations of 0.353 (17) and 0.647 (17). |
| Databáze: | Directory of Open Access Journals |
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