Pre-Recycling Material Analysis of NMC Lithium-Ion Battery Cells from Electric Vehicles

Autor: Anna Pražanová, Jan Kočí, Martin Havlík Míka, Dominik Pilnaj, Zbyněk Plachý, Vaclav Knap
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Crystals, Vol 13, Iss 2, p 214 (2023)
Druh dokumentu: article
ISSN: 2073-4352
DOI: 10.3390/cryst13020214
Popis: Environmental concerns push for a reduction in greenhouse gas emissions and technologies with a low carbon footprint. In the transportation sector, this drives the transition toward electric vehicles (EVs), which are nowadays mainly based on lithium-ion batteries (LIBs). As the number of produced EVs is rapidly growing, a large amount of waste batteries is expected in the future. Recycling seems to be one of the most promising end-of-life (EOL) methods; it reduces raw material consumption in battery production and the environmental burden. Thus, this work introduces a comprehensive pre-recycling material characterization of waste nickel-manganese-cobalt (NMC) LIB cells from a fully electric battery electric vehicle (BEV), which represents a basis for cost-effective and environmentally friendly recycling focusing on the efficiency of the implemented technique. The composition of the NCM 622 battery cell was determined; it included a LiNi0.6Co0.2Mn0.2O2 spinel on a 15 μm Al-based current collector (cathode), a graphite layer on 60 μm copper foil (anode), 25 μm PE/PVDF polymer separator, and a LiPF6 salt electrolyte with a 1:3 ratio in primary solvents DMC and DEC. The performed research was based on a series of X-ray, infrared (IR) measurements, gas chromatography–mass spectrometry (GC-MS), and inductively coupled plasma–optical emission spectrometry (ICP-OES) characterization of an aqueous solution with dissolved electrolytes. These results will be used in subsequent works devoted to optimizing the most suitable recycling technique considering the environmental and economic perspectives.
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