A Chiral Bis(salicylaldiminato)zinc(II) Complex with Second-Order Nonlinear Optical and Luminescent Properties in Solution

Autor: Paola Matozzo, Alessia Colombo, Claudia Dragonetti, Stefania Righetto, Dominique Roberto, Paolo Biagini, Simona Fantacci, Daniele Marinotto
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Inorganics, Vol 8, Iss 4, p 25 (2020)
Druh dokumentu: article
ISSN: 2304-6740
DOI: 10.3390/inorganics8040025
Popis: Whereas there is an increasing amount of reports on the second-order nonlinear optical (NLO) and luminescence properties of tetradentate [N2O2] Schiff base–zinc complexes, the study of zinc complexes having two bidentate [NO] Schiff-base ligands is relatively unexplored from an NLO point of view. This work puts in evidence that the known chiral bis{2-[(R)-(+)-1-phenylethyliminomethyl]phenolato-N,O}zinc(II) complex is a fascinating multifunctional molecular inorganic–organic hybrid material characterized by interesting second-order NLO and luminescent properties in solution. The emissive properties of the organic 2-(R)-(+)-1-phenylethyliminomethyl]phenol proligand are greatly enhanced upon coordination to the inorganic Zn(II) center.
Databáze: Directory of Open Access Journals
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