Crystal structures of two new 3-(2-chloroethyl)-r(2),c(6)-diarylpiperidin-4-ones

Autor:	K. Rajkumar, S. Sivakumar, R. Arulraj, Manpreet Kaur, Jerry P. Jasinski, A. Manimekalai, A. Thiruvalluvar
Jazyk:	angličtina
Rok vydání:	2018
Předmět:	crystal structure bifurcated bond weak intermolecular hydrogen bonds Crystallography QD901-999
Zdroj:	Acta Crystallographica Section E: Crystallographic Communications, Vol 74, Iss 4, Pp 483-486 (2018)
Druh dokumentu:	article
ISSN:	2056-9890 20569890
DOI:	10.1107/S2056989018003766
Popis:	The syntheses and crystal structures of 3-(2-chloroethyl)-r-2,c-6-diphenylpiperidin-4-one, C19H20ClNO, (I), and 3-(2-chloroethyl)-r-2,c-6-bis(4-fluorophenyl)piperidin-4-one, C19H18ClF2NO, (II), are described. The piperidone ring adopts a chair conformation in (I), whereas a slightly distorted chair conformation is formed in (II). The dihedral angle between the mean plane of the phenyl rings is 59.1 (1)° in (I) and 76.1 (1)° in (II). The crystal packing features weak intermolecular N—H...O hydrogen bonds in each structure.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/12f1528646134be5b9fa889fddc221da Zobrazit plný text záznamu View record in DOAJ