Bis[(4-methylphenyl)diphenylphosphine-κP](nitrito-κ2O,O′)silver(I)
| Autor: | Kariska Potgieter, Frederick P. Malan, Oyekunle Azeez Alimi, Reinout Meijboom |
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| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | IUCrData, Vol 7, Iss 8, p x220771 (2022) |
| Druh dokumentu: | article |
| ISSN: | 2414-3146 24143146 |
| DOI: | 10.1107/S2414314622007714 |
| Popis: | The title AgI complex, [Ag(NO2)(C19H17P)2], reveals a distorted pseudo-trigonal–planar shape around the AgI atom geometry resulting from the coordination of two phosphine ligands, as well as a nitrito-O,O′ ligand coordinating to the silver(I) atom through the oxygen atoms; in this description, the two oxygen atoms are assumed to occupy one position, forming an acute O—Ag—O angle of 51.44 (9)°. The plane resulting from the NO2 coordination to Ag is nearly perpendicular to the plane from the coordination of the phosphine-P atoms to Ag [dihedral angle = 86.43 (9)°]. |
| Databáze: | Directory of Open Access Journals |
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