‘Turn-on’ fluorescence sensing of Al(III) ions in water using a simple N-hydroxy-4-amino-1,8-naphthalimide chemosensor

Autor: Binduja Mohan, Jatin Kapoor, Ananthu Shanmughan, Mannanthara Kunhumon Noushija, Mayadevi Sumithradevi, Sankarasekaran Shanmugaraju
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Results in Chemistry, Vol 7, Iss , Pp 101402- (2024)
Druh dokumentu: article
ISSN: 2211-7156
DOI: 10.1016/j.rechem.2024.101402
Popis: A simple fluorophore, N-hydroxy-4-amino-1,8-naphthalimide (Nap-OH), has been designed and used as a fluorescent “turn-on” chemosensor for sensing metal cations in water. Nap-OH exhibited solvent-dependent photophysics in different solvents and displayed high selectivity and reversible sensing ability for Al(III) ions with femtomolar (10−15 M) sensitivity. The initial emission intensity of Nap-OH was drastically enhanced upon the addition of Al(III) ions and the calculated Stern-Volmer binding constant (KSV) is 4.70 × 104 M−1. The selective sensing of Al(III) was also reflected by sharp visual color changes and further demonstrated the use of Nap-OH for sensing Al(III) in real-water samples.
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