Determinação de manganês em material particulado atmosférico de ambientes de trabalho utilizando eletrodo de diamante dopado com boro e voltametria de onda quadrada com redissolução catódica
| Autor: | Felix Fabiana da Silva, Barros Rita de Cássia Mendes de, Lichtig Jaim, Masini Jorge C., Ferreira Neidenêi Gomes |
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| Jazyk: | English<br />Spanish; Castilian<br />Portuguese |
| Rok vydání: | 2005 |
| Předmět: | |
| Zdroj: | Química Nova, Vol 28, Iss 6, Pp 1000-1005 (2005) |
| Druh dokumentu: | article |
| ISSN: | 0100-4042 1678-7064 |
| Popis: | A boron-doped diamond electrode is used for determination of Mn(II) in atmospheric particulate matter by square wave cathodic stripping voltammetry. The analytical curve was linear for Mn(II) concentrations between 5.0 and 37.5 µg L-1, with quantification limit of 3.6 µg L-1. The precision was evaluated by the relative standard deviation, with values between 5.1% and 9.3%. The electrode is free of adsorption, minimizing memory effects. Samples collected in the workplace atmosphere of a foundry had Mn(II) concentrations between 0.4 and 4 µg m-3. No significant differences were observed between the proposed method and inductively coupled plasma optical emission spectroscopy. |
| Databáze: | Directory of Open Access Journals |
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