Reações de oxidação de derivados de cis-octalinas promovidas por trinitrato de tálio (TTN) Oxidation reactions of derivatives of cis-octalins promoted by thallium trinitrate (TTN)
| Autor: | Helena M. C. Ferraz, Vânia M. T. Carneiro, Tiago O. Vieira, Luiz F. Silva Jr. |
|---|---|
| Jazyk: | English<br />Spanish; Castilian<br />Portuguese |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Química Nova, Vol 31, Iss 4, Pp 781-787 (2008) |
| Druh dokumentu: | article |
| ISSN: | 0100-4042 1678-7064 |
| DOI: | 10.1590/S0100-40422008000400014 |
| Popis: | The reaction of ten cis-octalins and cis-octalones with thallium trinitrate (TTN) leads to different products, depending mainly on the substitution pattern of the substrate. Functionalized cis-hydrindanes were obtained from the reaction of 1,2,3,4,4a,5,8,8a-octahydro-4a-methylnaphthalene and of 1,2,3,4,4a,5,8,8a-octahydro-4a,7-dimethylnaphthalene with TTN in acetonitrile, whereas a cyclic ether was formed treating 1,2,3,4,4a,5,8,8a-octahydro-6,8a-dimethylnaphthalen-1-ol with TTN in trimethylorthoformate (TMOF). |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|