Hydroxylamine-mediated C–C amination via an aza-hock rearrangement

Autor: Tao Wang, Philipp M. Stein, Hongwei Shi, Chao Hu, Matthias Rudolph, A. Stephen K. Hashmi
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Nature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-021-27271-y
Popis: Syntheses of anilines occur through a variety of methods, most requiring transition metals or multiple steps. Here the authors disclose a protocol to form anilines from benzyl alcohols via an aza-Hock rearrangement that uses only a sulfonyl hydroxylamine and solvent.
Databáze: Directory of Open Access Journals