Metal-nonmetal transition in LixCoO2 thin film and thermopower enhancement at high Li concentration

Autor: Ishida, Y., Mizutani, A., Sugiura, K., Ohta, H., Koumoto, K.
Rok vydání: 2010
Předmět:
Zdroj: Phys. Rev. B 82, 075325 (2010)
Druh dokumentu: Working Paper
DOI: 10.1103/PhysRevB.82.075325
Popis: We investigate the transport properties of LixCoO2 thin films whose resistivities are nearly an order of magnitude lower than those of the bulk polycrystals. A metal-nonmetal transition occurs at ~0.8 in a biphasic domain, and the Seebeck coefficient (S) is drastically increased at ~140 K (= T*) with increasing the Li concentration to show a peak of magnitude ~120 \muV/K in the S-T curve of x = 0.87. We show that T* corresponds to a crossover temperature in the conduction, most likely reflecting the correlation-induced temperature dependence in the low-energy excitations.
Databáze: arXiv