Phase diagram analysis and crystal growth of solid solutions Ca_{1-x}Sr_xF_2

Autor: Klimm, D., Rabe, M., Bertram, R., Uecker, R., Parthier, L.
Rok vydání: 2007
Předmět:
Zdroj: Journal of Crystal Growth 310 (2008)152-155
Druh dokumentu: Working Paper
DOI: 10.1016/j.jcrysgro.2007.09.031
Popis: The binary phase diagram CaF$_2$--SrF$_2$ was investigated by differential thermal analysis (DTA). Both substances exhibit unlimited mutual solubility with an azeotropic point showing a minimum melting temperature of T_\mathrm{min}=1373^{\circ}$C for the composition Ca$_{0.582}$Sr$_{0.418}$F$_2$. Close to this composition, homogeneous single crystals up to 30 mm diameter without remarkable segregation could be grown by the Czochralski method.
Comment: accepted for publication in J. Crystal Growth
Databáze: arXiv