Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework
| Autor: | Carter, Joseph H., Han, Xue, Moreau, Florian Y., da Silva, Ivan, Nevin, Adam, Godfrey, Harry G. W., Tang, Chiu C., Yang, Sihai, Schröder, Martin |
|---|---|
| Rok vydání: | 2018 |
| Předmět: | |
| Zdroj: | Journal of the American Chemical Society Carter, J H, Han, X, Moreau, F Y, Da Silva, I, Nevin, A, Godfrey, H G W, Tang, C C, Yang, S & Schröder, M 2018, ' Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal–Organic Framework ', Journal of the American Chemical Society, vol. 140, no. 46, pp. 15564-15567 . https://doi.org/10.1021/jacs.8b08433 |
| ISSN: | 0002-7863 |
| DOI: | 10.1021/jacs.8b08433 |
| Popis: | We report a record-high SO2 adsorption capacity of 12.3 mmol g-1 in a robust porous material, MFM-601, at 298 K and 1.0 bar. The SO2 adsorption in MFM-601 is fully reversi-ble and highly selective over CO2 and N2. The binding do-mains for adsorbed SO2 and CO2 molecules in MFM-601 have been unambiguously determined by in situ synchro-tron X-ray diffraction experiments, giving insights at the molecular level to the basis of the observed high selectivity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|