Crystal structure of (2-acetyl-ferrocen-1-yl)boronic acid
| Autor: | Andrea, Preuss, Marcus, Korb, Heinrich, Lang |
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| Rok vydání: | 2018 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications |
| ISSN: | 2056-9890 |
| Popis: | In the crystal structure of (2-acetylferrocen-1-yl)boronic acid, centrosymmetric dimers held together by –B(OH)⋯O hydrogen bonds are present. (2-Acetylferrocen-1-yl)boronic acid, [Fe(C5H5)(C7H8BO3)] or 2-C(O)CH3-1-B(OH)2–Fc [Fc = Fe(η5-C5H3)(η5-C5H5)], crystallizes in the centrosymmetric space group P21/n. The boronic acid functionality interacts via intramolecular hydrogen bonds with the acetyl group and with the –B(OH)2 functionality of an adjacent molecule. The resulting centrosymmetric dimer exhibits an anti-positioning of the ferrocenyl moieties towards the central B2O4 plane. Consequently, an (Rp,Sp)-, i.e. a meso configuration is present for this dimer. In the crystal, weak C—H⋯O hydrogen bonds consolidate the molecular packing. |
| Databáze: | OpenAIRE |
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