Novel chlorinated tropanes derived from the treatment of cocaine with sodium hypochlorite

Autor:	J F, Casale, J M, Moore, D A, Cooper
Rok vydání:	1995
Předmět:	Flame Ionization Cocaine Isomerism Molecular Structure Sodium Hypochlorite Criminology Chlorine Oxidation-Reduction Gas Chromatography-Mass Spectrometry Mass Spectrometry Tropanes
Zdroj:	Journal of forensic sciences. 40(5)
ISSN:	0022-1198
Popis:	Several novel chlorinated tropanes were produced when cocaine was treated with aqueous sodium hypochlorite. Two of these, 2'- and 3'-chlorobenzoyloxy-2-carbomethoxypseudotropine (that is, ortho- and meta-chlorococaine), were characterized by synthesis and gas chromatography/mass spectrometry. Four other new chlorinated tropanes (endo-6- and 7-chlorococaine, exo-6- or 7-chlorococaine and N-chlorobenzoylnorecgonine methyl ester) were also tentatively identified via their gas chromatography retention data and mass spectra. The results are of potential use in cocaine signature and comparative analysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=pmid________::f09c22aa77d6ce11448b0c3bf3941000 https://pubmed.ncbi.nlm.nih.gov/7595328 Zobrazit plný text záznamu