Diastereoselective synthesis of a spironoraristeromycin using an acylnitroso Diels-Alder reaction

Autor:	Weimin, Lin, Kristopher G, Virga, Kyung-Hee, Kim, Jaroslav, Zajicek, David, Mendel, Marvin J, Miller
Rok vydání:	2009
Předmět:	Models Molecular Adenosine Molecular Conformation Stereoisomerism Article Nitroso Compounds Substrate Specificity
Zdroj:	The Journal of organic chemistry. 74(16)
ISSN:	1520-6904
Popis:	The tert-butyl N-hydroxycarbamate-derived nitroso reagent 1 reacted with N-Cbz-protected spirocyclic diene 2 to provide spirocycloadduct 3. Here we describe the efficient conversion of 3 into the novel carbocyclic nucleoside spironoraristeromycin 4.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=pmid________::e93c98e09dbdd88ef7d12aa1317f41a8 https://pubmed.ncbi.nlm.nih.gov/19601571 Zobrazit plný text záznamu