Transformation of 2,2'-bimorphine to the novel compounds 10-alpha-S-monohydroxy-2,2'-bimorphine and 10,10'-alpha,alpha'-S,S'-dihydroxy-2,2'-bimorphine by Cylindrocarpon didymum
Autor: | P J, Stabler, P J, Holt, N C, Bruce |
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Rok vydání: | 2001 |
Předmět: | |
Zdroj: | Applied and environmental microbiology. 67(8) |
ISSN: | 0099-2240 |
Popis: | Whole-cell suspensions of Cylindrocarpon didymum were observed to transform 2,2'-bimorphine to the compounds 10-alpha-S-monohydroxy-2,2'-bimorphine and 10,10'-alpha,alpha'-S,S'-dihydroxy-2,2'-bimorphine. Mass spectrometry and (1)H nuclear magnetic resonance spectroscopy confirmed the identities of these new morphine alkaloids. |
Databáze: | OpenAIRE |
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