Metal-to-metal electron transfer in a cyanido-bridged {Fe

Autor: Corine, Mathonière, Dmitri, Mitcov, Evangelia, Koumousi, Daniel, Amorin-Rosario, Pierre, Dechambenoit, Sadaf, Fatima Jafri, Philippe, Sainctavit, Christophe, Cartier Dit Moulin, Loic, Toupet, Elzbieta, Trzop, Eric, Collet, Marie-Anne, Arrio, Andrei, Rogalev, Fabrice, Wilhelm, Rodolphe, Clérac
Rok vydání: 2022
Zdroj: Chemical communications (Cambridge, England). 58(86)
ISSN: 1364-548X
Popis: The switching properties of a cyanido-bridged Fe/Co square molecule were investigated by single-crystal X-ray diffraction and X-ray absorption spectroscopy at both Fe and Co K-edges. Combining these two techniques, a complete picture of the thermal-, light- and X-ray-induced metal-to-metal electron transfer is obtained, illustrating the concerted role played by the Fe and Co sites.
Databáze: OpenAIRE