| Autor: |
Alan R, Hoskinson, Wilson T, Rawlins, Kristin L, Galbally-Kinney, Emily, Gong, Jeffrey, Hopwood |
| Rok vydání: |
2023 |
| Předmět: |
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| Zdroj: |
J Phys D Appl Phys |
| ISSN: |
0022-3727 |
| Popis: |
We have used arrays of microwave-generated microplasmas operating at atmospheric pressure to generate high concentrations of singlet molecular oxygen, O(2)((1)Δ(g)), which is of interest for biomedical applications. The discharge is sustained by a pair of microstrip-based microwave resonator arrays which force helium/oxygen gas mixtures through a narrow plasma channel. We have demonstrated the efficacy of both NO and less-hazardous N(2)O additives for suppression of ozone and associated enhancement of the O(2)((1)Δ(g)) yield. Quenching of O(2)((1)Δ(g)) by ozone is sufficiently suppressed such that quenching by ground state molecular oxygen becomes the dominant loss mechanism in the post-discharge outflow. We verified the absence of other significant gas-phase quenching mechanisms by measuring the O(2)((1)Δ(g)) decay along a quartz flow tube. These measurements indicated a first-order rate constant of (1.2 ± 0.3) × 10(−24) m(3) s(−1), slightly slower than but consistent with prior measurements of singlet oxygen quenching on ground state oxygen. The discharge-initiated reaction mechanisms and data analysis are discussed in terms of a chemical kinetics model of the system. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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