| Autor: |
Rihards, Aleksis, Andrew J, Pell |
| Rok vydání: |
2020 |
| Zdroj: |
The Journal of chemical physics. 153(24) |
| ISSN: |
1089-7690 |
| Popis: |
We develop a theoretical framework for a class of pulse sequences in the nuclear magnetic resonance (NMR) of rotating solids, which are applicable to nuclear spins with anisotropic interactions substantially larger than the spinning frequency, under conditions where the radiofrequency amplitude is smaller than or comparable to the spinning frequency. The treatment is based on average Hamiltonian theory and allows us to derive pulse sequences with well-defined relationships between the pulse parameters and spinning frequency for exciting specific coherences without the need for any detailed calculations. This framework is applied to the excitation of double-quantum spectra of |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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