Activation of TEMPO by ClO

Autor: Timo, Pääkkönen, Raili, Pönni, Jinze, Dou, Markus, Nuopponen, Tapani, Vuorinen
Rok vydání: 2017
Zdroj: Carbohydrate polymers. 174
ISSN: 1879-1344
Popis: Bromide-free TEMPO-catalyzed oxidation of the primary alcohols by sodium hypochlorite (NaOCl) does not proceed without a prior activation of the catalyst. Here were demonstrate an immediate in situ activation of the catalyst with an equimolar addition of chlorine dioxide (ClO
Databáze: OpenAIRE