Chloridobis(dimethyl-glyoximato-κN,N')(4-methyl-pyridine-κN)cobalt(III) hemihydrate
| Autor: | Madhavan, Amutha Selvi, Kannan, Arun Kumar, Arunachalam, Dayalan |
|---|---|
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| Popis: | In the title complex, [Co(C(4)H(7)N(2)O(2))(2)Cl(C(6)H(7)N)]·0.5H(2)O, the central Co(III) ion, chelated by four N atoms of the two bidenate glyoximate ligands, exhibits a slightly distorted octa-hedral geometry. The axial positions are occupied by a chloride ion and the 4-methyl-pyridine N atom. Inter-molecular O-H⋯O hydrogen bonds link the mol-ecules in the crystal via the water mol-ecules, while the glyoximate ligands exhibit intra-molecular O-H⋯O hydrogen bonds. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|