Octahedral rhenium cluster complexes with inner organic ligands: synthesis, structure and properties of [Re6Q8(3,5-Me2PzH)6]Br2·2(3,5-Me2PzH) (Q = S, Se)

Autor: Mironov, Y., Bryleva, K., Shestopalova, M., Yarovoia, S., Fedorova, V., Spies, H., Pietzsch, H.-J., Stephan, H., Geipel, G., Bernhard, G., Kraus, W.
Jazyk: angličtina
Rok vydání: 2006
Zdroj: Inorganica Chimica Acta (2006)359, 1129-1134
Popis: Two new octahedral cluster complexes – [Re6S8(3,5-Me2PzH)6]Br2·2(3,5-Me2PzH) (1) and [Re6Se8(3,5-Me2PzH)6]Br2·2(3,5-Me2PzH) (2), where 3,5-Me2PzH is 3,5-dimethyl-pyrazole, have been synthesized using reaction of rhenium chalcobromide complexes Cs4[Re6S8Br6]·2H2O and Cs3[Re6Se8Br6]·H2O respectively with molten 3,5-dimethylpyrazole. Both compounds synthesized were characterised by X-ray single-crystal diffraction and chemical analysis, IR and luminescent spectra.
Databáze: OpenAIRE