Synthesis of calcium doped phosphate tungsten bronze

Autor: Maksimović, Tijana, Maksimović, Jelena, Stojadinović, Stevan, Tančić, Pavle, Nedić, Zoran
Jazyk: angličtina
Rok vydání: 2018
Předmět:
Zdroj: Proceedings-14th International Conference on Fundamental and Applied aspects of Physical Chemistry-Physical Chemistry 2018, September 24-28, 2018 Belgrade, Serbia
Popis: A study is presented of phase transitions of acid CaHPW12O40∙6H2O salt of 12-tungstophosphoric acid and characterized in the temperature range from room temperature to 1093 K. The structure and its phase transformations were characterized by thermal analysis (TGA and DSC), X-ray powder diffraction (XRPD) and Fourier-transform infrared spectra (FTIR). Dehydration processes are finished at about 770 K. Keggin’s anions are transformed by solid-solid recrystallization at about 873 K in calcium doped phosphate tungsten bronze.
Databáze: OpenAIRE