Nuclear-quadrupole interactions in perovskite-type compounds of hf/sup 181/ studied by the perturbed-angular-correlation technique
Autor: | Andrade, Pedro da Rocha, Forker, Manfred, Rogers, John David, Kunzler, Julio Vitor |
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Jazyk: | angličtina |
Rok vydání: | 1972 |
Předmět: | |
Zdroj: | Repositório Institucional da UFRGS Universidade Federal do Rio Grande do Sul (UFRGS) instacron:UFRGS |
Popis: | Measurements of nuclear-quadrupole-interaction constants in perovskite-type compounds of PbHf03, SnHf03, CaHf03, and SrHf03 have been performed using the perturbed-angularcorrelation technique. A range of fundamental frequencies from 150 x 106 to 550 x 106 rad/sec was determined. The variation of the quadrupole constants has been discussed through the molecular-orbital theory. A semiempirical formula for the admixture coefficient between d wave functions and p wave functions which describes the covalent bonding present in each AB03 compound has been derived. |
Databáze: | OpenAIRE |
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