Absolute configuration of anabasine from Messor and Aphaenogaster ants

Autor:	Leclercq, Sabine, Charles, Sébastien, Daloze, Désiré, Braekman, Jean Claude, Aron, Serge, Pasteels, Jacques
Jazyk:	angličtina
Rok vydání:	2001
Předmět:	Aphaenogaster Chromatography Gas Ants -- chemistry Ethologie Ants Messor Insecticides -- analysis Plants Anabasine -- chemistry Anabasine -- analysis Anabasine Insecticides -- chemistry Alkaloids Animals Absolute configuration
Zdroj:	Journal of Chemical Ecology, 27
Popis:	A method has been developed to assign the absolute configuration and enantiomeric excess of anabasine based on small amounts of material (in the microgram range), by derivatization with (+)-menthylchloroformate followed by capillary GC analysis of the resulting carbamate(s). This method was applied to three samples of anabasine isolated from Messor and Aphaenogaster ants. In Messor sanctus, only (2'S)-anabasine was present, whereas in Aphaenogaster subterranea and A. miamiana (2'S)-anabasine was determined to have an ee of 78 and 24%, respectively. Journal Article Research Support, Non-U.S. Gov't info:eu-repo/semantics/published
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=od______2101::37c01c30b1263b31e9b29e8a6a9e9b3f http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/18709 Zobrazit plný text záznamu