| Autor: |
Lu, Peng, Ghosh, Supriya, Dorneles de Mello, Matheus, Kamaluddin, Huda Sharbini, Li, Xinyu, Kumar, Gaurav, Duan, Xuekui, Abeykoon, Milinda, Boscoboinik, J Anibal, Qi, Liang, Dai, Heng, Luo, Tianyi, Al-Thabaiti, Shaeel, Narasimharao, Katabathini, Khan, Zaheer, Rimer, Jeffrey D, Bell, Alexis T, Dauenhauer, Paul, Mkhoyan, K Andre, Tsapatsis, Michael |
| Rok vydání: |
2021 |
| Předmět: |
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| Zdroj: |
Angewandte Chemie (International ed. in English), vol 60, iss 35 |
| Popis: |
Synthesis of a pentasil-type zeolite with ultra-small few-unit-cell crystalline domains, which we call FDP (few-unit-cell crystalline domain pentasil), is reported. FDP is made using bis-1,5(tributyl ammonium) pentamethylene cations as structure directing agent (SDA). This di-quaternary ammonium SDA combines butyl ammonium, in place of the one commonly used for MFI synthesis, propyl ammonium, and a five-carbon nitrogen-connecting chain, in place of the six-carbon connecting chain SDAs that are known to fit well within the MFI pores. X-ray diffraction analysis and electron microscopy imaging of FDP indicate ca. 10 nm crystalline domains organized in hierarchical micro-/meso-porous aggregates exhibiting mesoscopic order with an aggregate particle size up to ca. 5 μm. Al and Sn can be incorporated into the FDP zeolite framework to produce active and selective methanol-to-hydrocarbon and glucose isomerization catalysts, respectively. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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