Base-induced elimination reactions. VII. Hydroxide-promoted elimination reactions: alkyl halides as substrates

Autor:	Schlosser, Manfred, Tarchini, Claudio
Předmět:	RACT (Reactant or reagent) (dehydrobromination of Alkyl bromides Role: RCT (Reactant) by potassium hydroxide) Alkyl chlorides Role: RCT (Reactant) RACT (Reactant or reagent) (dehydrochlorination of alkyl halide dehydrohalogenation catalyst Solvent effect (in dehydr
Popis:	HCl and HBr were easily abstracted from secondary and tertiary alkyl halides by KOH in tetraglyme, but primary alkyl halides yielded approx. equal amts. of elimination and substitution products (alkenes and alcs. and/or ethers). However, the addn. of catalytic amts. of Me3N favored dehydrohalogenation via quaternary ammonium salt intermediates. [on SciFinder (R)]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=od_______185::71eb3f0d459bd2ce02526c796ed0fb6d https://infoscience.epfl.ch/record/81512 Zobrazit plný text záznamu