| Autor: |
Ohzuku, Tsutomu, Sawai, Keijiro, Hirai, Taketsugu |
| Jazyk: |
angličtina |
| Rok vydání: |
1984 |
| Zdroj: |
Memoirs of the School of Engineering, Okayama University. 18(1):57-73 |
| ISSN: |
0475-0071 |
| Popis: |
Basic kinetic equations of chronopotentiometric potential-time curves, in which the equations for reversible, quasi-reversible and irreversible electron transfer process appeared in special cases, were given and a chronopotentiometric method for determining kinetic parameters was proposed therefrom. The method was demonstrated for Fe(3+)/Fe(2+) redox reaction in acidic aqueous media. The limitations of the method and the double-layer charging effects on the potential-time curve were discussed. The extension of the method to more general electrode processes was also considered. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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