Symmetry breaking in single-crystal SrTiO3 plates: EPR manifestations

Autor: V. A. Trepakov, S. I. Nikitin, I. N. Gracheva, D. G. Zverev, B. F. Gabbasov, Alexander Rodionov, Alexandr Dejneka, Airat Kiiamov, R. V. Yusupov, Lubomir Jastrabik
Rok vydání: 2021
Předmět:
Zdroj: Europhysics Letters. 133:37002
ISSN: 1286-4854
0295-5075
Popis: Electron paramagnetic resonance studies of the impurity Fe$^{3+}$ and Mn$^{4+}$ centers indicate that the symmetry of the crystal structure of millimeter-scale strontium titanate plates above 105 K lowers in the bulk from cubic to tetragonal, different from that of the conventional low-temperature antiferrodistortive phase. It is shown that the effect does not originate from the residual stress; its magnitude (observed tetragonal distortion) and particular manifestations depend on plate orientation, surface quality and the geometry of a sample. Peculiarities of the observed phenomenon are presented and possible scenario of its realization is discussed.
14 pages, 4 figures
Databáze: OpenAIRE