Sulfonylation of Benzylic C−H Bonds through the Reaction of Aryl(o -tolyl)methanones with Sulfonyl Hydrazides or Sulfonyl Chlorides

Autor:	Jie Wu, Wenlin Xie, Jiahao Chen, Xinxing Gong, Xiaofang Li
Rok vydání:	2018
Předmět:	Sulfonyl chemistry.chemical_classification Reaction mechanism 010405 organic chemistry Aryl Radical Organic Chemistry General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Medicinal chemistry 0104 chemical sciences chemistry.chemical_compound chemistry Reagent
Zdroj:	Chemistry - An Asian Journal. 13:2543-2548
ISSN:	1861-4728
DOI:	10.1002/asia.201800591
Popis:	A sulfonylation of benzylic C-H bonds of aryl(o-tolyl)methanones with arylsulfonyl hydrazides or arylsulfonyl chlorides has been developed. Arylsulfonyl hydrazides and arylsulfonyl chlorides were employed as sulfonylating reagents respectively to complete this transformation. During the reaction, enols were generated in situ from aryl(o-tolyl)methanones under UV irradiation, and subsequently reacted with sulfonyl radicals to provide a range of aryl(2-(arylsulfonylmethyl)aryl)methanones.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f9856181708e72e9c1af723e128f3bd9 https://doi.org/10.1002/asia.201800591 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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