Dynamic Responsive Systems for Catalytic Function
| Autor: | Matea Vlatković, Beatrice S. L. Collins, Ben L. Feringa |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
010402 general chemistry
01 natural sciences Catalysis redox chemistry Organic chemistry PHOTOSWITCHABLE ORGANOCATALYSIS molecular switches Molecular switch EPSILON-CAPROLACTONE photochemistry 010405 organic chemistry Chemistry ENANTIOSELECTIVE CATALYSIS Catalytic function Organic Chemistry General Chemistry Responsive systems SIGNAL AMPLIFICATION homogeneous catalysis ALLOSTERIC CATALYST 0104 chemical sciences RING-OPENING POLYMERIZATION OLEFIN METATHESIS CATALYSTS Epsilon-caprolactone HETEROGENEOUS CATALYSIS PHOTORESPONSIVE MOLECULAR SWITCH Biochemical engineering photoswitchable systems Signal amplification REDOX CONTROL |
| Zdroj: | Chemistry. 22(48):17080-17111 |
| ISSN: | 0947-6539 |
| DOI: | 10.1002/chem.201602453 |
| Popis: | Responsive systems have recently gained much interest in the scientific community in attempts to mimic dynamic functions in biological systems. One of the fascinating potential applications of responsive systems lies in catalysis. Inspired by nature, novel responsive catalytic systems have been built that show analogy with allosteric regulation of enzymes. The design of responsive catalytic systems allows control of catalytic activity and selectivity. In this Review, advances in the field over the last four decades are discussed and a comparison is made amongst the dynamic responsive systems based on the principles underlying their catalytic mechanisms. The catalyst systems are sorted according to the triggers used to achieve control of the catalytic activity and the distinct catalytic reactions illustrated. |
| Databáze: | OpenAIRE |
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