Crystal structure ofN,N′-[(ethane-1,2-diyl)bis(azanediylcarbonothioyl)]bis(benzamide)
| Autor: | Elhadj Ibrahima Thiam, Rokhaya Sylla-Gueye, Issa Samb, Pascal Retailleau, Nango Gaye, Mohamed Gaye |
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| Rok vydání: | 2019 |
| Předmět: |
Quantitative Biology::Biomolecules
crystal structure Crystallography Hydrogen bond Thio Ethylenediamine General Chemistry Crystal structure Condensed Matter Physics Medicinal chemistry humanities benzoylthioureido Crystal chemistry.chemical_compound Benzoyl chloride chemistry Thiourea QD901-999 Physics::Atomic and Molecular Clusters Molecule General Materials Science Physics::Chemical Physics thiourea ethylenediamine |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 5, Pp 642-645 (2019) |
| ISSN: | 2056-9890 |
| Popis: | The reaction of benzoyl chloride and ethylendiamine in the presence of potassium thiocyanate yielded a white solid, C18H18N4O2S2, which consists of two benzoylthioureido moieties connected by an ethylene chain. The asymmetric unit consists of one half of the molecule, the complete molecule being generated by crystallographic inversion symmetry. Both thiourea moieties are in atransconformation. An intramolecular N—H...O hydrogen bond occurs. In the crystal, C—H...S and C—H...O hydrogen bonds link the molecules, forming layers parallel to theacplane. |
| Databáze: | OpenAIRE |
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