Threading of three rings on two stations: a convergent approach to [4]rotaxane

Autor:	Yuchen Liu, Along Jia, Yidan Zhou, Lihua Yuan, Jinyang Wu, Weitao Xu, Menglong Liu, Zejiang Liu, Xin Xiao, Xiaowei Li
Rok vydání:	2021
Předmět:	Rotaxane Materials science Metals and Alloys General Chemistry Catalysis Forging Surfaces Coatings and Films Electronic Optical and Magnetic Materials Chemical physics Materials Chemistry Ceramics and Composites Threading (manufacturing) Molecule Single crystal
Zdroj:	Chemical Communications. 57:13506-13509
ISSN:	1364-548X 1359-7345
Popis:	A novel approach to efficient and selective construction of [4]rotaxane was proposed to demonstrate the superiority of H-bonded azo-macrocycles in forging higher order rotaxanes. The single crystal structure reveals the importance of the interplay of multiple non-covalent bonding interactions, particularly π-stacking interactions, in stabilizing the host-guest complex. This may open an avenue to the synthesis of oligomeric mechanically interlocked molecules containing fewer stations but more rings.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f57f18dca4d594e25b50f67ff0e65fc7 https://doi.org/10.1039/d1cc05501a Zobrazit plný text záznamu