Crystal structure of 3-benzamido-1-(4-nitrobenzyl)quinolinium trifluoromethanesulfonate
| Autor: | Iván J. Bazany-Rodríguez, Mariana Nicolas-Gomez, Simón Hernández-Ortega, Alejandro Dorazco-González, Eduardo Plata-Vargas |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
crystal structure
Stereochemistry benzamide Crystal structure Dihedral angle 010402 general chemistry 01 natural sciences Research Communications Crystal chemistry.chemical_compound Amide p-nitrobenzylquinolinium p-nitrobenzylquinolinium General Materials Science Benzamide Crystallography 010405 organic chemistry Chemistry trifluoromethanesulfonate salt Methane sulfonate General Chemistry Condensed Matter Physics 0104 chemical sciences QD901-999 Nitro trifluoromethanesulfonate salt |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 5, Pp 747-750 (2016) Acta Crystallographica Section E: Crystallographic Communications |
| ISSN: | 2056-9890 |
| Popis: | In the title salt, each cation shows a moderate distortion between the planes of the amide groups and the quinolinium rings. The trifluoromethanesulfonate anions are linked to organic cations via N—H⋯O hydrogen-bonding interactions involving the NH amide groups. In the crystal, weak C—H⋯O hydrogen bonds and π-stacking interactions between the quinolinium and phenyl rings link the organic cations into chains. In the title compound, C23H18N3O3 +·CF3SO3 −, the asymmetric unit contains two crystallographically independent organic cations with similar conformations. Each cation shows a moderate distortion between the planes of the amide groups and the quinolinium rings with dihedral angles of 14.90 (2) and 31.66 (2)°. The quinolinium and phenyl rings are slightly twisted with respect to each other at dihedral angles of 6.99 (4) and 8.54 (4)°. The trifluoromethanesulfonate anions are linked to the organic cations via N—H⋯O hydrogen-bonding interactions involving the NH amide groups. In the crystal, the organic cations are linked by weak C—H⋯O(nitro group) interactions into supramolecular chains propagating along the b-axis direction. |
| Databáze: | OpenAIRE |
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