Isocyanide Insertion-Cyclization Reaction for Imidazoisoindol-5-imine Scaffold Synthesis: A Selective Solvatochromic Fluorescent Probe for Methanol Detection

Autor:	Yaser Balmohammadi, Hamid Reza Goli, Fereshteh Ahmadi, Ayoob Bazgir
Rok vydání:	2020
Předmět:	Scaffold Cyanides Molecular Structure Isocyanide Methanol Organic Chemistry Solvatochromism Imine Bond formation Combinatorial chemistry Fluorescence Catalysis chemistry.chemical_compound chemistry Cyclization Imines Fluorescent Dyes
Zdroj:	The Journal of organic chemistry. 86(1)
ISSN:	1520-6904
Popis:	An efficient, ligand-free, and Pd-catalyzed method for the synthesis of imidazoisoindole imine scaffolds with satisfactory yields via C-C and C-N bond formation has been developed. The synthesized scaffolds have unique potential for selective MeOH detection from other solvents, especially EtOH. The appealing features of this transformation are phosphinic ligand-free conditions, the use of a small amount of Pd(OAc)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f35f270c835277482666830fe015a450 https://pubmed.ncbi.nlm.nih.gov/33295761 Zobrazit plný text záznamu