Mono- and bis-tolylterpyridine iridium(III) complexes
| Autor: | Victor G. Young, Lindsay M. Hinkle, Kent R. Mann |
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| Rok vydání: | 2010 |
| Předmět: |
Stereochemistry
Dimethyl sulfoxide Center (category theory) chemistry.chemical_element Space group General Medicine Crystal structure Medicinal chemistry General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound chemistry Molecule Iridium Terpyridine Acetonitrile Metal-Organic Compounds |
| Zdroj: | Acta Crystallographica Section C Crystal Structure Communications. 66:m62-m64 |
| ISSN: | 0108-2701 |
| DOI: | 10.1107/s0108270110002751 |
| Popis: | The first structure report of trichlorido[4'-(p-tolyl)-2,2':6',2''-terpyridine]iridium(III) dimethyl sulfoxide solvate, [IrCl(3)(C(22)H(17)N(3))] x C(2)H(6)OS, (I), is presented, along with a higher-symmetry setting of previously reported bis[4'-(p-tolyl)-2,2':6',2''-terpyridine]iridium(III) tris(hexafluoridophosphate) acetonitrile disolvate, [Ir(C(22)H(17)N(3))(2)](PF(6))(3) x 2 C(2)H(3)N, (II) [Yoshikawa, Yamabe, Kanehisa, Kai, Takashima & Tsukahara (2007). Eur. J. Inorg. Chem. pp. 1911-1919]. For (I), the data were collected with synchrotron radiation and the dimethyl sulfoxide solvent molecule is disordered over three positions, one of which is an inversion center. The previously reported structure of (II) is presented in the more appropriate C2/c space group. The iridium complex and one PF(6)(-) anion lie on twofold axes in this structure, making half of the molecule unique. |
| Databáze: | OpenAIRE |
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