A Hydronium Solvate Ionic Liquid: Facile Synthesis of Air-Stable Ionic Liquid with Strong Brønsted Acidity
| Autor: | Shun Takeoka, Kuniaki Murase, Kohei Kintsu, Kazuhiro Fukami, Takashi Nagata, Masayuki Saimura, Atsushi Kitada, Masato Katahira |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Hydronium
010405 organic chemistry Renewable Energy Sustainability and the Environment Chemistry Inorganic chemistry hydronium 010402 general chemistry Condensed Matter Physics 01 natural sciences 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound solvate ionic liquid Ionic liquid Materials Chemistry Electrochemistry acidity |
| Zdroj: | Journal of The Electrochemical Society. 165:H121-H127 |
| ISSN: | 1945-7111 0013-4651 |
| DOI: | 10.1149/2.0481803jes |
| Popis: | A new kind of ionic liquid (IL) with strong Brønsted acidity, i.e., a hydronium (H₃O⁺) solvate ionic liquid, is reported. The IL can be described as [H₃O⁺·18C6]Tf₂N, where water exists as the H₃O⁺ ion solvated by 18-crown-6-ether (18C6), of which the counter anion is bis(trifluoromethylsulfonyl)amide (Tf₂N⁻; Tf = CF₃SO₂). The hydrophobic Tf₂N⁻ anion makes [H₃O⁺·18C6]Tf₂N, evaluated using the indicator method, is a new record for ILs and indicates strong aciditiy. The findings regarding this proton-condensed solvate IL are of fundamental interest, and will help in the design of media for new acid-base reactions. This was Paper 3475 presented at the Honolulu, Hawaii, Meeting of the Society, October 2–7, 2016. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|